基于ICP-MS/MS技术测定食用植物油中22种微量元素
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国家自然科学基金面上项目(81603400);湖南省教育厅重点科研项目(14A035);湖南省应用特色学科材料科学与工程学科资助项目(湘教通[2018]469号)


Determination of 22 Kinds of Trace Elements in Edible Vegetable Oil Using ICP-MS/MS
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    摘要:

    基于电感耦合等离子体串联质谱(ICP-MS/MS)测定食用植物油中的22种微量元素。食用植物油样品采用煤油稀释后直接进样分析,在MS/MS模式下,分别采用H2、O2、NH3/He为反应气,使干扰物或分析物与反应气发生质量转移反应,利用原位质量法或质量转移法消除质谱干扰。结果:各待测元素线性关系良好,线性相关系数≥0.9996。22种元素的检出限在0.35~307.84 pg/g范围。采用加标回收法验证方法的准确性,加标回收率在96.60%~105.46%之间,相对标准偏差(RSD)≤3.99%。采用所建立的方法分别测定来自国内不同地区的菜籽油、花生油、葵花籽油、玉米油和橄榄油等常用食用植物油,结果显示:5种食用植物油中P、S、K、Na、Ca的含量较高,而重金属元素Cr、As、Cd、Hg、Pb的含量很低。该方法具有样品处理简单、灵敏度高、检出限低的特点,能准确监控食用植物油中的营养性元素和安全性元素。

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    A simple analytical method for the determination of 22 kinds of trace elements in edible vegetable oil was established by inductively coupled plasma tandem mass spectrometry (ICP-MS/MS). The edible vegetable oil samples were diluted with kerosene and then directly injected for analyzing. In the MS/MS mode, H2, O2, and NH3/He were used as the reaction gas, with whom the interferences or analytes will react, as a result the mass spectrometry interferences were eliminated by on-mass method or mass-shift method. The analytes showed good linearity with linear correlation coefficient ≥ 0.9996, and the detection limit was 0.35-307.84 pg/g. The accuracy of the method was verified by spiked recovery experiment. The spike recoveries ranged from 96.60% to 105.46%, and the relative standard deviation (RSD) is ≤ 3.99%. The edible vegetable oil, such as rapeseed oil, peanut oil, sunflower oil, corn oil and olive oil, from different parts of China were determined by this established method. The results reveal that the contents of P, S, K, Na and Ca in the five kinds of edible vegetable oil were higher, while the contents of As, Cd, Hg and Pb were low. The analytical method has the characteristics of simple sample processing, high sensitivity and low detection limit, and can accurately monitor the nutritive elements and heavy elements in edible vegetable oil.

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张萍;刘宏伟.基于ICP-MS/MS技术测定食用植物油中22种微量元素[J].中国食品学报,2019,19(12):250-257

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  • 在线发布日期: 2020-01-09
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