包装材料阻隔性能对黄酒风味的影响
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(1.江南大学食品学院 粮食发酵工艺与技术国家工程实验室 江苏无锡 214122;2.上海石库门酿酒有限公司 上海 201501)

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国家自然科学基金面上项目(31701593,31771968);


Effects of Barrier Properties of Packaging Materials on the Flavor of Huangjiu
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(1.National Engineering Laboratory for Cereal Fermentation Technology, School of Food Science,Jiangnan University, Wuxi 214122, Jiangsu;2.Shanghai Shikumen Wine Co. Ltd., Shanghai 201501)

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    摘要:

    中国市场上的黄酒普遍采用复合膜袋、玻璃瓶、陶瓷瓶、塑料桶及利乐枕等包装形式,不同包装材料的阻隔性能差异较大,对成品黄酒的风味产生不同的影响。为了检测不同包装材料中黄酒风味的变化情况,通过压差法,库仑计检测法,杯式法,红外传感器法,浊度检测法,固相微萃取法和酒精度、总酸、总糖、氨基酸态氮检测法对包装材料的氧气透过率和水蒸气透过率,黄酒的浊度,醇、酯、醛的含量和理化指标进行检测。经试验发现,复合膜的阻隔性能最差,氧气透过率和水蒸气透过率均很高分别为1 448 cm3/(m2·24 h·0.1 MPa)和2.09 g/(m2·24 h)。成品酒贮存3~6个月内,已经出现明显的风味损失,贮存1年后,出现大量沉淀。因此阻隔性能较差的包装材料不适合作为黄酒的包装使用。塑料桶的阻隔性能居中,氧气透过率虽较高,但水蒸气透过率较低。HDPE塑料桶会加速酒体的氧化,使得浊度和多种挥发性物质含量上升,不利于保持风味的稳定性,货架期应设置在1年以内。利乐包、玻璃瓶和陶瓷瓶的阻隔性能较好,氧气透过率和水蒸气透过率均较低。贮存1年后,沉淀较少,且黄酒风味含量保持相对稳定。对贮存1~17年的玻璃瓶包装产品进行了理化指标和风味分析,产品品质良好,仍然适合饮用。黄酒中大部分风味物质含量保持稳定,但在微溶氧的影响下,醛类化合物的含量上升,说明黄酒贮存在玻璃容器中,也发生陈酿的变化。

    Abstract:

    In Chinese market, rice wine is generally packaged in composite film bags, glass bottles, ceramic bottles, plastic buckets and Tetra pak pillows. The barrier properties of different packaging materials are quite different, which have different effects on the flavor of the finished rice wine. In order to detect the change of flavor of rice wine in different packaging materials, the oxygen transmittance and water vapor transmittance of packaging materials, the turbidity of rice wine, the contents of alcohol, ester and aldehyde and the physicochemical indexes were detected by the pressure difference method, coulommeter detection method, cup method, infrared sensor method, turbidity detection method, solid phase microextraction method and the detection methods of alcohol, total acid, total sugar and amino acid nitrogen. It was found that the composite membrane had the worst barrier performance, and the permeability of oxygen and water vapor were very high, which were 1 448 cm3/ (m2·24 h·0.1 MPa) and 2.09 g/(m2·24 h), respectively. The finished wine had obvious flavor loss within 3-6 months of storage, and a large amount of precipitation appears after storage for 1 year. Therefore, packaging materials with poor barrier properties were not suitable for packaging rice wine. The barrier performance of the plastic drum was in the middle, the oxygen transmission rate was high, but the water vapor transmission rate was low. HDPE plastic bucket would accelerate the oxidation of the wine body, making the turbidity and the content of a variety of volatile substances rise, which was not conducive to maintaining the stability of the flavor, and the shelf life should be set within 1 year. Tetra pak, glass bottles and ceramic bottles had better barrier properties, and lower oxygen and water vapor transmission rates. After storage for 1 year, the precipitation was less, and the flavor content of rice wine remained relatively stable. The physical and chemical indexes and flavor of the glass bottle packaging products stored for 1-17 years were analyzed. The quality of the products was good and they were still suitable for drinking. The content of most flavor substances in rice wine remained stable, but the content of aldehyde compounds increased under the influence of slightly dissolved oxygen. This indicated that the rice wine is stored in glass containers, and the aging changes also occur.

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胡健,黄媛媛,刘桂孝,刘双平,毛健.包装材料阻隔性能对黄酒风味的影响[J].中国食品学报,2023,23(11):246-253

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  • 收稿日期:2022-11-09
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  • 在线发布日期: 2023-12-14
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