小分子糖-罗望子多糖复合凝胶特性研究
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(1.上海理工大学健康科学与工程学院 上海食品微生物工程技术研究中心 上海 200093;2.云南猫哆哩集团食品有限责任公司 云南玉溪 653100)

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上海市科技创新行动计划国内科技合作项目(21015800300)


Studies on the Gelling Properties of Complex between Small Molecular Sugars and Tamarind Seed Polysaccharide
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(1.Shanghai Engineering Research Center of Food Microbiology, School of Health Science and Engineering,University of Shanghai for Science and Technology, Shanghai 200093;2.Yunnan Maoduoli Group Food Co., Ltd., Yuxi 653100, Yunnan)

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    摘要:

    探究不同小分子糖(蔗糖、果糖和葡萄糖)含量对罗望子多糖(TSP)复合凝胶特性的影响。分析小分子糖-TSP复合凝胶的流变特性、持水性、质构特性,并通过低场核磁共振技术分析其水分分布情况。结果表明:质量分数45%~60%的蔗糖和果糖及质量分数40%~55%的葡萄糖能使1%(m/V)的TSP溶液形成凝胶;当蔗糖和果糖的质量分数为55%,葡萄糖质量分数为50%时,蔗糖-TSP复合凝胶的G′、持水性、硬度、内聚性和咀嚼性分别为108.39 Pa,98.20%,65.55 g,0.87和52.55 g,果糖-TSP复合凝胶的G′、持水性、硬度和咀嚼性分别为147.36 Pa,98.57%,62.29 g和44.84 g,葡萄糖-TSP复合凝胶的G′、持水性、硬度、内聚性分别为117.46 Pa,98.56%,61.86 g和48.05 g,都达到最大值,此时凝胶性质最稳定,最有嚼劲。低场核磁结果表明,当蔗糖和果糖质量分数为55%,葡萄糖质量分数为50%时,小分子糖-TSP复合凝胶半结合水含量为99.8%~100%,可能是小分子糖中的羟基与水分子形成较多的氢键,半结合水大幅度增加,TSP链之间交联增多,使得凝胶更加坚固。研究结果可为TSP在食品工业中的应用提供理论依据。

    Abstract:

    The effects of different content of small molecular sugars (sucrose, fructose and glucose) on the properties of tamarind seed polysaccharide (TSP) composite gel were investigated. The rheology properties, water holding capacity and texture of small molecular sugar-TSP gel were studied. The moisture distributions of the composite gels were analyzed by low-field nuclear magnetic resonance (LF NMR). The results showed that sucrose and fructose at 45%-60% (m/m) and glucose at 40%-55%(m/m) could make TSP solution (1%, m/V) form gel. When the contents of sucrose and fructose at 55% (m/m) and glucose at 50%(m/m), the G′, water holding capacity, hardness, cohesiveness and chewiness of sucrose-TSP gel were of 108.39 Pa, 98.20%, 65.55 g, 0.87, 52.55 g, while the G′, water holding capacity, hardness and chewiness of fructose-TSP gel were of 147.36 Pa, 98.57%, 62.29 g, 44.84 g, and the G′, water holding capacity, hardness, cohesiveness of glucose-TSP gel were of 117.46 Pa, 98.56%, 61.86 g, 48.05 g, all of which reached the maximum. At this state, the gels were the most stable and chewable. The results of LF NMR showed that when sucrose and fructose at 55% (m/m) and glucose at 50% (m/m), the semi-bound water content of small molecular sugar-TSP gels was 99.8%-100%. This might be due to the large amount of hydrogen bonds between hydroxy groups of small molecular sugars and water molecules, and the cross-linking between TSP chains increased, which made the gel much stronger. This study can provide theoretical basis for the application of tamarind polysaccharide in food industry.

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王枫,艾连中,赖凤羲,张汇,谢凡,宋子波.小分子糖-罗望子多糖复合凝胶特性研究[J].中国食品学报,2024,24(4):69-79

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  • 收稿日期:2023-08-08
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  • 在线发布日期: 2024-05-24
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