茶渣碱提果胶的流变性质及其食用膜的制备
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(1.福州大学生物科学与工程学院 福州 350108;2.福建省食品生物技术创新工程技术研究中心 福州 350108;3.福州大学先进制造学院 食品营养与健康研究中心 福建晋江 362200;4.福州市青瓦生物科技有限公司 福州 350108)

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国家自然科学基金青年科学基金项目(31701649)


Rheological Properties of Alkali-extracted Pectin from Tea Residue and Preparation of Its Edible Film
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(1.College of Biological Science and Engineering, Fuzhou University, Fuzhou 350108;2.Fujian Food Biotechnology Innovation Engineering Technology Research Center, Fuzhou 350108 ;3.Food Nutrition and Health Research Center, College of Advanced Manufacturing, Fuzhou University,Jinjiang 362200, Fujian;4.Fuzhou Cyan-tile Biotech Co., Ltd., Fuzhou 350108)

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    摘要:

    茶渣中含有约10%的果胶,用碱法提取的果胶产物(ATRP)可作为食用薄膜原料。以ATRP为原料,测定其基本组分,探究果胶质量浓度和添加Ca2+浓度对ATRP流变性质的影响。以ATRP为基材,分别添加海藻酸钠、魔芋葡甘聚糖和羧甲基纤维素钠制备果胶薄膜,探究其抗拉伸延展性的变化。结果表明,ATRP中主链HG结构域占比为72.3%,支链RG-I结构域占比为24.0%,其溶液为非牛顿流体。当ARTP质量浓度达70 g/L时,其溶液黏度为5×104 mPa·s,形成凝胶的储存模量(G′)为157 Pa,损耗模量(G″)为21 Pa,凝胶转换点在300 s-1处出现。与40 g/L ARTP溶液相比,其黏度和凝胶强度显著提高。此外,在40 g/L的ARTP溶液中添加Ca2+后,其黏度和凝胶强度的最高幅度分别可达到原始值的80倍和20倍,而其添加量不超过30 mmol/L。与单一ATRP薄膜相比,复合薄膜具有更完整的外观与更优异的抗拉伸延展性。其中,ATRP-魔芋葡甘聚糖按体积比1∶1制备的复合薄膜的抗拉伸延展性最强,最大承受拉力为280 g(拉伸时间为70 s),是单一ATRP薄膜最大承受拉力的7倍,最大延展性的70倍。

    Abstract:

    Tea residue contains approximately 10% pectin, which has the potential to serve as a raw material for edible film production. In this study, alkali-extracted tea residue pectin (ATRP) was employed that its basic composition was determined, and the influence of pectin concentration and the addition of Ca2+ on the rheological properties of ATRP was investigated. Edible films were prepared using ATRP as the matrix material, combined with sodium alginate, konjac glucomannan, and sodium carboxymethyl cellulose, to explore the changes in tensile elongation. The results showed that the ATRP contained 72.3% HG domain, while the side chain 'RG-I domain' accounted for 24.0%, and the solution exhibited non-Newtonian fluid behavior. When the ATRP mass concentration reached 70 g/L, the viscosity of the solution was 5×104 mPa·s, and the resulting gel showed a storage modulus (G′) of approximately 157 Pa and a loss modulus (G″) of approximately 21 Pa, and the gelation transition occurred at 300 s-1, demonstrating a significant increase in viscosity and gel properties compared to the 40 g/L ATRP solution. Furthermore, after adding Ca2+ to a 40 g/L ARTP solution, the maximum increases in its viscosity and gel strength could reach 80 times and 20 times their original values, respectively. but the Ca2+ concentration should not exceed 30 mmol/L. Compared to the film made by only ATRP, the films made by complex reagents exhibited improved appearance and superior tensile elongation properties. Among them, the film made by ATRP - konjac glucomannan (prepare according to a volume ratio of 1∶1) showed the highest tensile elongation, with a maximum load of 280 g (at a stretching time of 70 s), which was seven times higher than that of film made by only ATRP and 70 times higher in terms of elongation. Therefore, ATRP exhibits promising potential as a raw material for edible film production.

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彭莉莉,杨新,李伟强,王梦田,张晨.茶渣碱提果胶的流变性质及其食用膜的制备[J].中国食品学报,2024,24(11):50-58

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  • 收稿日期:2023-11-19
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  • 在线发布日期: 2024-12-25
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