日晒海盐中微塑料检测技术对比研究
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(1.中国农业大学食品科学与营养工程学院 北京 100083;2.中国农业科学院农产品加工研究所 北京 100193)

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Comparative Study on Detection Techniques of Microplastics from Solarized Sea Salt
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(1.College of Food Science and Nutritional Engineering, China Agricultural University, Beijing 100083;2.Institute of Food Science and Technology, Chinese Academy of Agricultural Sciences, Beijing 100193)

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    摘要:

    微塑料(MPs)为一种新型食品安全风险因子,会通过食物链的累积进入人体,从而带来严重的健康风险问题。为探究海产品中MPs是否存在及其潜在风险,以日晒海盐为研究对象,采用30% H2O2的氧化剂消解法为样品前处理方法,去除海盐中的有机杂质,并分别采用目视法、显微镜观察法、显微傅里叶红外光谱法和显微拉曼光谱法等多种典型检测技术确认海盐中是否存在MPs。结果:上述3种方法所得海盐样品中MPs的数量分别为2 550,(750±200)个/kg和(1 500±500)个/kg,颜色以白色和无色为主,少量红色、蓝色和黑色,聚合物类型包括聚酯、尼龙和聚丙烯。结论:通过比较上述检测方法的优势和局限性,发现显微拉曼光谱法能够更准确地对微塑料进行定性和定量,为日晒海盐中MPs的风险预警提供一定的技术支撑。

    Abstract:

    As a new type of food safety risk factor, microplastics (MPs) can accumulate into the human body through the food chain, resulting in serious health risk issues. In order to explore the existence and potential risks of MPs in seafoods, we took solarized sea salt as the representative research object. Firstly, we removed organic impurities in sea salt by using 30% H2O2 oxidant digestion as pretreatment method. Then, we confirmed the existence of MPs in sea salt by visual method, microscopic observation, microscopic fourier infrared spectroscopy, and microscopic Raman spectroscopy. Results: through visual analysis, microscopic fourier infrared spectroscopy, and microscopic Raman spectroscopy, it was found that the number of MPs in sea salt samples is approximately 2 550/kg, (750±200)/kg, and (1 500±500)/kg, with white and colorless colors as the main colors, and a small amount of red, blue, and black. Polymer types included polyester, nylon, and polypropylene. Conclusion: by comparing the advantages and limitations of common detection methods. it was determined that micro-Raman spectroscopy is more effective for both qualitative and quantitative analysis of microplastics. It will provide certain technical support for the risk warning of MPs in solarized sea salt.

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张琪,宋光春,黄昆仑,罗云波,程楠.日晒海盐中微塑料检测技术对比研究[J].中国食品学报,2024,24(12):323-331

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  • 收稿日期:2023-12-15
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  • 在线发布日期: 2025-01-23
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