Pyran Derivative Sensing Gelatin Dual-Channel Indication of Fish Freshness
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(1.College of Chemistry and Materials Engineering, College of Food Science and Engineering, National & Local Joint Engineering Research Center of Storage, Processing and Safety Control Technology for Fresh Agricultural and Aquatic Products, Bohai University, Jinzhou 121013, Liaoning;2.College of Ecological and Environmental Engineering, Qinghai University, Xining 810000)

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    Abstract:

    In this paper, an amine-sensitive fluorescent probe CHM was designed and synthesized using benzopyran as a fluorophore by introducing an electron-withdrawing group tricyanofuran to extended conjugated system. The probe can recognize 11 amines with an off-on fluorescence response, a large Stokes shift (120 nm), a low detection limit (putrescine, 1.3 μmol/L) in EtOH/H2O (5/5, V/V) solution, and can imaging for putrescine in living cells. Probe CHM is loaded onto the gelatin to obtain sensing gelatin CHMGL. CHMGL shows significant color changes to volatile amines, which can be used to monitor the freshness of salmon fish in real time through colorimetric and fluorescence dual-channels, and can accurately judge the freshness of fish.

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  • Received:October 14,2023
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  • Online: December 16,2024
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